How Galileo Found the Density of Air

(Two New Sciences, Page 79)

 

As to the other question, namely, how to determine the specific gravity of air, I have employed the following method. I took a rather large glass bottle with a narrow neck and attached to it a leather cover, binding it tightly about the neck of the bottle: in the top of this cover I inserted and firmly fastened the valve of a leather bottle, through which I forced into the glass bottle, by means of a syringe, a large quantity of air. And since air is easily condensed one can pump into the bottle two or three times its own volume of air. After this I took an accurate balance and weighed this bottle of compressed air with the utmost precision, adjusting the weight with fine sand. I next opened the valve and allowed the compressed air to escape; then replaced the flask upon the balance and found it perceptibly lighter: from the sand which had been used as a counterweight I now removed and laid aside as much as was necessary to again secure balance. Under these conditions there can be no doubt but that the weight of the sand thus laid aside represents the weight of the air which had been forced into the flask and had afterwards escaped. But after all this experiment tells me merely that the weight of the compressed air is the same as that of the sand removed from the balance; when however it comes to knowing certainly and definitely the weight of air as compared with that of water or any other heavy substance this I cannot hope to do without first measuring the volume [quantità] of compressed air; for this measurement I have devised the two following methods.

 

According to the first method one takes a bottle with a narrow neck similar to the previous one; over the mouth of this bottle is slipped a leather tube which is bound tightly about the neck of the flask; the other end of this tube embraces the valve attached to the first flask and is tightly bound about it. This second flask is provided with a hole in the bottom through which an iron rod can be placed so as to open, at will, the valve above mentioned and thus permit the surplus air of the first to escape after it has once been weighed: but his second bottle must be filled with water. Having prepared everything in the manner above described, open the valve with the rod; the air will rush into the flask containing the water and will drive it through the hole at the bottom, it being clear that the volume [quantità] of water thus displaced is equal to the volume [mole e quantità] of air escaped from the other vessel. Having set aside this displaced water, weigh the vessel from which the air has escaped (which is supposed to have been weighed previously while containing the compressed air), and remove the surplus of sand as described above; it is then manifest that the weight of this sand is precisely the weight of a volume [mole] of air equal to the volume of water displaced and set aside; this water we can weigh and find how many times its weight contains the weight of the removed sand, thus determining definitely how many times heavier water is than air; and we shall find, contrary to the opinion of Aristotle, that this is not 10 times, but, as our experiment shows, more nearly 400 times.

 

The second method is more expeditious and can be carried out with a single vessel fitted up as the first was. Here no air is added to that which the vessel naturally contains but water is forced into it without allowing any air to escape; the water thus introduced necessarily compresses the air. Having forced into the vessel as much water as possible, filling it, say, three-fourths full, which does not require any extraordinary effort, place it upon the balance and weigh it accurately; next hold the vessel mouth up, open the valve, and allow the air to escape; the volume of the air thus escaping is precisely equal to the volume of water contained in the flask. Again weigh the vessel which will have diminished in weight on account of the escaped air; this loss in weight represents the weight of a volume of air equal to the volume of water contained in the vessel.